There are two ways to get Amazon ebooks onto your computer. One way is to send them to a registered Kindle and either copy them from the device using calibre or download to your computer the link for the book Amazon sends you in an email. The second way is to put the Kindle for PC/Mac application on your computer, register it to your Amazon account, and send the book you purchase to the application. Then you can add the .azw book file (found in the Documents/My Kindle Content folder on your computer I think) that corresponds to the book to calibre.
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