Here's what the chapter code looks like from Book Designer when opened in Sigil:
Code:
<p><span id="title"><a id="BdToc_1"></a></span></p>
<div class="sgc-3">
<span class="sgc-6" id="title">1 Technician</span>
</div>
When the same HTM file is dragged into Calibre, some changes seem to get made during the process. This is the same chapter location;
Code:
<h2 class="title"><a id="BdToc_1"></a></h2>
<div class="sgc-3">
<h2 class="title sgc-6">1 Technician</h2>
</div>
It now contains h2 tags. It looks like something more still has to be done with this before a true TOC can be generated in either Sigil or Calibre. I'll have to fiddle with this to see if I can get it to work.