I use Digital Editions to transfer a book to my PE, and then use a file explorer (ES or the eDGe library "device storage" browser) to "add it to library." So long as I'm operating within my library's two-week lending window, it opens fine for me in e-ink.
Fun fact: so long as you leave a lended book open on the e-ink side, you can keep reading it, even if the lending period has expired. (Further dirty pool: if you keep setting the date back in the eDGe system settings, you can open it indefinitely. Which is a decidedly lesss-than-ideal way of living your life, but might come in handy if you still have a chapter or two to go on virtual return-day.)
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