Ok a few more that spring to mind
Fantasy setting, but really it's more sci-fi in it's themes and philosophy:
CJ Cherryh - The Morgaine Chronicles
Ursula K. Le Guin - the Earthsea novels (fantasy)
Ursula K. Le Guin - The Left Hand of Darkness (brilliant sci-fi, though a little dated now. come on this is where the Ansible concept came from!)
And speaking of the Ansible:
Orson Scott Card - Ender's Game (and other novels in that setting)
...don't think I saw ^^^^ mentioned already.
Ok that's it for now, but keep 'em coming everyone! My 505 arrives *tomorrow* so I'm crazy about stocking up on ebooks.