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The most likely cause for this is an error in the source. I suspect you're seeing Sigil choke on some of the obscure tags that Word produces. Make sure you save as 'Web Page (filtered)' to get rid of some of the worst of the junk that Word throws in.
There are better ways to get xhtml out of a Word document, such as atlantis Word Processor or Writer2ePub with Open Office.
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