FYI, I managed to get my problem book downloaded (but not properly in my library). I clicked to add it to my library as Unread, went to the Copia reader and Synced. The book now shows in my book list. Double clicking downloaded the book and let me read it. On the web, it still shows that I can buy it (which means it isn't "mine" in the library), but I no longer care.
Try this on your problem books...
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