Very Easy
Just go to your Amazon account and manage your Kindle. Even if you don't have an actual Kindle and are just using the "Kindle for Mac" or Kindle iPhone App you can select whatever book you've just bought to be sent to either device no matter what your original selection was (e.g., iphone). In this case select "Deliver to 'Kindle for Mac'" and it is done within seconds... no jailbreaking needed.
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