XP installs have always been easy for me.
I suggest that your Anti-virus or other system error got in the way.
Start clean:
delete the Calibre2 folder in Program files.
delete all previous Calibre downloads
Reboot
Now run the chkdsk.exe to fix file system errors.
Reboot
Now download a fresh copy of Calibre from the official site
Disable your A/V
Install Calibre
(post the exact error, if any)
Re-enable your A/V
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