As above you need to deauthorise the reader by ADE and then authorise it because you will not be able to read the book without first downloading it via ADE.
When you download ADE I think it puts a file in your documents folder called My digital editions. Then when you purchase and download the book it will send an ACSM file to that folder. You can then open ADE and drag the file over to ADE and it will download the actual book, which after connecting your reader you will be able to drop it onto.
Hope that helps
Mike
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