As soon as you convert, the docx (xml) will be converted to xhtml. This WILL result in loss of some items that are specific for the Word format. Again, you either need to change the epub (not docx) yourself or ask Smashword to convert better.
You did not respond to my earlier question. What does Flightcrew (validator of Sigil) say when you put the epub from Smashwords through it?
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