The process NatCh describes is accurate for everything except the first reader (in my experience). I'm not sure why, but I was unable to select the first reader for de-authorization. I could select the PC and second reader, but not the first one (my first reader died and I got a replacement). It may be that this is the primary device for each account and without it, an account has little meaning, so they prevent you from de-authorizing it. I had to send Sony Support an email and ask for help. They took care of it quickly.
PCH
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