Books downloaded to your Kindle have no copy on the pc. If you download for a Kindle, to your PC, and save the copy somewhere, or use Kindle4PC, and download to that, then you will have a copy on your pc. You control, during the download, where the copies go. I think Kindle4PC uses some directory name like "My Kindle Content", but downloading via the browser does not work that way. Depending on what browser you use, and what its settings are, there may be a default download area. I use FireFox, and tell it to always ask where to put the file. Then I know where it is going.
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