Probably your best option for large PDFs would be an old Irex Iliad. It's no longer in production and has no support, but it does have a large screen.
The problem is that it also has a number of power-hungry features that tend to defeat the purpose of choosing EInk because the battery life is not good.
If you're not going for reflowable PDFs, the reflective TFT devices such as the Jetbook/Aluratek products are probably your worst option. PDFs benefit from large screens and these have both small (5") screens and the lowest resolution (640x480) of any of the mainstream devices.
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