I went through a few cards, found that some of the cheaper ones are worth what you pay for them. Yea . . . . ADATA... I'm pointing at you! IMHO Transcend makes good cards, go with class 6 or better for boot cards.
As far as space... your nook came with 5gb, so anything equal or better should be good to go. I've seen people claim all the way up to 32 gb on the android forums. THAT would be a LOT of books.... Keep in mind that you lose access to the 5gb on your NC (unless you dual boot and go back and forth) and cannot access internal storage material if your SD booting.
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