Hello Gromet, welcome to MobileReader.
Yes, if you register your wife's Sony Reader to the same account that you have yours registered to, you'll be able to share books. You can have up to 6 devices (a device is either a Sony Reader or a PC) registered to the same account.
One small thing, by the way, which I should mention. There is an eBook format called "eReader" (which the Sony can't read) and it gets horribly confusing if people refer to the Sony Reader as an "eReader". Best to call it the "Sony Reader" to avoid the potential for confusion.
Best wishes,
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