Default fonts for Calibre viewer appear to be:
Serif = Times New Roman
Sans-serif = Verdana
Monospaced = Courier New
Default font = Serif
I've attached a screen shot showing the same single and double curly quote characters in a range of different fonts - shows how much exactly the same characters can change in appearance depending on the font used to display them. These are all TrueType fonts - most should either be already installed or available as free downloads.
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