Thanks for your reply! This is what I found out:
Where are my ebook files located?
The Sony Library doesn’t move files "into" the Library, the Library just maintains a pointer to the actual file on your hard drive or other media.
Windows:
If you downloaded them using ADE, the folder is <your username>/documents/My Digital Editions
If you downloaded them using the sony software, the folder is <your username>/documents/My Books/Reader Library
Annotations File
This is an xml file that stores any annotations.
Windows:
C:\Users\dsteiner\AppData\Local\Sony Corporation\Reader\Database\kLibrary.xdb
Mac:
/Users/username/Library/Preferences/Sony Corporation/Reader/Database/kLibrary
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