Hmm, so it's a reg key problem.
I'm a bit miffed how mine ended up like this as I have been using the 64bit versions since Valloric started creating them and initially never had a problem.
I'd manually change the install path to Program Files (the 64bit one) in the wizard during the install process, I'd never set it as the default and always had it working on the "Open With" option. After installing over the top of (I think) 0.1.8 (64bit) with 0.1.9 (64bit) I suddenly lost this ability and had to add Sigil to the "Send To" option to get it to work.
Strange.
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