If you log into Amazon and then go to your account, you'll find a link to "Manage my Kindle" (link is also provided near the top of the page in the Kindle Store). Your Kindle's email address is listed on that page. That's also where you can, if necessary, add "trusted" email addresses from which you can email documents to your kindle - by default, that list will start out containing just the email address you have registed with Amazon, but if you want to be able to use other email addresses to send documents to your Kindle, you can add them on this page.
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