To get the book into Calibre, you would need to find it in the ADE folder on your computer, not the ADE program itself. For me, ADE books are in Documents > My Digital Editions. Copy the book from there to Calibre and you will be able to move it to another location like a reader, but you will not be able to open it or convert it because Calibre cannot open or convert anything that is DRM-infested.
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