I am using the same type of set-up as you are suggesting with great success. I have a PRS-650 that I am using with my Macbook to read books primarily downloaded from my local library. I also use Calibre (on a netbook running Ubuntu) with books from Project Gutenberg, converting to epub, and moving the books to an SD card for use in my reader.
Personally, I am thrilled with my 650 and couldn't imagine anything more perfect for reading books.
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