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vivienna is correct. Your file association with .acsm files is screwed up somehow.If you are using Firefox and you purchase an ebook it should ask you what to do with .ascm files at which point you can browse to Adobe Digital Editions and save the setting for future purchases.
Otherwise you can go into Windows Explorer and select folder options from the Tools menu then file types and find the acsm entry and change it to ADE and all should be sweet.
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