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I don't think you can turn off sync. If you can, I'd love to know how.
If your Sony Library software is syncing constantly (and it's not because you're making changes to the books in the library), try this. Turn off the auto-launch feature (in sony library preferences). Then connect the Reader. Use Windows Explorer to look at the Reader's file system. Find the Cache folder and delete media.xml. Disconnect the reader and let it start up. After start up is complete, try connecting the reader and launch the Sony Library software.
Hope that helps.
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