I think that the Kindle is shipped with English as the primary language and that you have to choose a different language. I could be wrong about that.
As for the books you can buy, check the Amazon store right now. You should be able to see what type of books you can buy with a Spanish address and credit card. If you feel that the selection is limited there are posts in the Kindle board that can help you get around the geographic restrictions.
If you are a native English speaker I am assuming that you are not a Spanish citizen or you perhaps have dual citizenship. If that is the case and you are a British Subject or American Citizen then you should have legal access to one of those two stores.
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