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Is this an ebook from Amazon? If so, it probably has DRM (encryption) and is locked to your K4PC account. In most cases you can have the same Kindle ebook on 6 devices, but you have to download it separately for each device. Either use whispernet, or download it from your manage Kindle page to your computer (indicating your K2 as the target). Then side load it via USB to Kindle\documents on your K2.
If it isn't from Amazon and you can read it on K4PC, then, as mldavis2 said, just copy it from My Documents\My Kindle Content via USB to Kindle\documents on your K2.
If you want a DRM-free MOBI version of a K4PC AZW from Amazon, then see Apprentice Alf's Blog and don't forget to look in the comments. The new tools_v2.0 bundle seems to be the eaiest yet to use.
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