Do you think 5-6 seconds are too long? Time your office program, for example (or whatever you use to work in). I'm sure it takes a lot longer than 5 seconds to start up.
I don't know what them power-users do, but why would I want Calibre to start on boot? That only makes sense if I wanted it to fetch some news right away, and even that could be managed in a better way via the CLI tools.
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