I've actually never tried to open the acsm files the way you describe. Usually I just double click on them or open them into ADE when downloading them from the library. Your library uses the overdrive system? I'm going to assume yes, as that is most common. If so it should behave basically like mine. So, go back to your library ebook site where you "checked out" the books. Go to your account page to the "My Checked Out Items". For each book, click the download button again. It should prompt/ask whether you want to save the file or Open it with ADE. Choose Open with ADE. ADE should launch and attempt to download the real book. Then you should see the epub files in your "My Digital Editions" folder.
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