Weird but this worked for me...
I was having a problem with my PRS-505 not syncing, it would just sit on processing forever and I had a problem with duplicates within the library on the device. All I did was cancel the sync, and go in and uncheck the sync library checkbox under the Sync category under the device. Then I just grabbed one of the books from the local library and dragged it into the reader and voila it sync'd and everything is good...
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