Try in your Goodreads account deauthorising the previous "application" to start again. You can do this by clicking on the dropdown arrow next to your name on the top right of the website, choosing "my account", click on the "apps" tab and then scroll to the bottom of the screen where you will see the "GoodReads Calibre GUI plugin" and click on the "Revoke Access" button next to it.
Now start the whole authorisation process over in the plugin.
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