It could be a faulty charger, do you know someone who has a PSP charger you can borrow to see if the PRS600 will charge with that?
Did you get the official charger or did you buy a cheap PSP charger? If you have an non-Sony charger you might want to check the voltage (5V or better 5,2V) and the Amps (the higher the quicker it charges, don't know what's the minimum for the PRS).
Good luck!
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