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No there isn't and there never will be. In MOBI, the metadata toc is the content toc. Clicking the go to table of contents button in a kindle takes you to the content toc, not the metadata toc. That may well have changed with newer kindle firmware, I haven't kept track, but it nonetheless means that the vast majority of MOBI6 files have complete content TOCs and incomplete metadata TOCs. For instance, many MOBI files have flattened versions of the toc in their NCX Tocs.
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