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DOCX files are ZIP archives. Open them up (or is it "expand" on a Mac?) and compare the same image that you processed in Photoshop, against the same image that Word processed.
If you save it as a JPG in Photoshop, then import it into Word - which also saves it as JPG - then you're doing it wrong. Saving from a lossy format to another lossy format is a bad idea.
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