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I am not familar with Mac. As for Word 2000, I don't think there's an option to inspect the document, but you can view the source of a HTML file.
Hmm....when you convert epub back to rtf, I am not sure if it will create more junk or not though. If I'm you, I would convert PDF to HTML and clean it first before converting HTML to EPUB. But I am no expert. You may want to get some help from the Calibre or EPUB forum.
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