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Personally I believe sync causes too many problems, I prefer to keep that option off. What you can do to manually turn it off is open your reader thru My Computer as if it was a removable disk.
You will find there a folder called database, and inside this you will find another one called sync. Delete this folder. This will prevent SRL from syncing automatically.
Then move your books (and your collections) manually by dragging and dropping.
Regarding your other questions, the double arrow on the corner means the book has been synced with your library so it cannot be deleted directly. But after you delete the folder I told you those arrows should be gone and you will be able to delete books.
As for the blue? (do you mean pink or purple?) ball that means the book is new and unread.
Hope I helped a bit!
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