You cannot connect iOS devices to the main Calibre on Linux via USB as that requires iTunes to be present and there is no Linux version of iTunes.
For iOS devices you therefore have to connect over the network to the Calibre Content server (not the main Calibre program). This allows the library to be accessed either as HTML pages via a browser (e.g. Safari), or as an OPDS catalog if you have suitable OPDS compatible apps such as MegaReader/QuickReader, Stanza or eBook Search.
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