It is annoying but if you go in to the application Image Capture on your Mac when your Kindle is connected you can then set a preference so that it does nothing in the future.
I am on Snow Leopard, so I have to do it for each piece of image holding hardware I connect, I'm not sure about older software.
I've got a feeling there is a bit of applescript one can download which opens Image Capture automatically the first time you connect a fresh new image holding device so that you can set the preference more easily, but I cannot find it now.
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