I had this problem once and it turned out to be a corrupted font file. The Finder tries to show the font in the icon and it appeared to hang on the corrupted font file. When I looked at the "fonts" directory they all showed the font in the icon except the one. When I tried to "Get Info" on that file it gave an error. I deleted that font set and it's worked fine since.
btw You might have to restart and run the Disk Utility repair on both volumes first.
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